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Int. , 42, 980. C. (2003) Chem. Eur. , 9, 5181. 23 24 1 Introduction 38. M. (2000) Pure Appl. , 51. -P. ) (1999) Transition Met- 72, 2265. J. (1967) J. Am. Chem. , 89, 7019. A. (2004) Angew. , 116, 1311; (2004) Angew. Chem. Int. , 43, 1291. F. I. (2003) Angew. , 115, 802; (2003) Angew. Chem. Int. , 42, 778. Anderson, S. L. Templates in Organic Synthesis: Definitions and Roles, in Ref. 34e,. -P. and Dietrich-Buchecker, C. (eds) (1999) Molecular Catenanes, Rotaxanes, and Knots, Wiley-VCH Verlag GmbH, Weinheim.

N. (2002) Angew. , 114, 4647; (2002) Angew. Chem. Int. N. (2004) J. Am. Chem. , and Kuipers, L. (2004) J. Am. Chem. , 126, 1577. F. (2004) Science, 303, 1845. S. (1991) New J. T. (1991) Science, 254, 1312; (c) Philp, D. F. (1996) Angew. , 108, 1243; (1996) Angew. Chem. Int. , and Albrecht, M. (2004) Chem. Eur. , 10, 1072. D. R. L. W. Steed), Dekker, New York, p. 1257. Klug, A. (1983) Angew. , 95, 579; (1983) Angew. , Int. Ed. , 22, 565. F. M. (2000) Self-Assembly in Supramolecular Chemistry, Royal Society of Chemistry, Cambridge.

Originating from the question as to how living organisms came into existence, self-replication is a special, but certainly intriguing case of supramolecular catalysis. If one thinks about the complex ribosome, which nowadays transcribes genetic information stored in nucleic acids into proteins, which then become involved in the duplication of DNA, it is immediately clear that this apparatus is much too complex to self-organize accidentally at the beginning of life. Instead, much simpler mechanisms must have existed in the early world.

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Analytical Methods in Supramolecular Chem. [2 vols] by C. Schalley


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